{"id":137,"date":"2015-11-12T14:53:11","date_gmt":"2015-11-12T13:53:11","guid":{"rendered":"https:\/\/members.ifimac.uam.es\/fjgarcia\/?p=137"},"modified":"2025-01-31T19:56:32","modified_gmt":"2025-01-31T18:56:32","slug":"pronounced-photovoltaic-response-from-multilayered-transition-metal-dichalcogenides-pn-junctions","status":"publish","type":"post","link":"https:\/\/members.ifimac.uam.es\/fjgarcia\/research-highlights\/articles\/pronounced-photovoltaic-response-from-multilayered-transition-metal-dichalcogenides-pn-junctions\/","title":{"rendered":"Pronounced Photovoltaic Response from Multilayered Transition-Metal Dichalcogenides PN-Junctions"},"content":{"rendered":"<p><img loading=\"lazy\" decoding=\"async\" class=\"size-full wp-image-138 aligncenter\" src=\"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-content\/uploads\/sites\/19\/2025\/01\/nano_letters-2015-03265a.jpg\" alt=\"Pronounced Photovoltaic Response from Multilayered Transition-Metal Dichalcogenides PN-Junctions - Featured\" width=\"840\" height=\"375\" srcset=\"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-content\/uploads\/sites\/19\/2025\/01\/nano_letters-2015-03265a.jpg 840w, https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-content\/uploads\/sites\/19\/2025\/01\/nano_letters-2015-03265a-300x134.jpg 300w, https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-content\/uploads\/sites\/19\/2025\/01\/nano_letters-2015-03265a-768x343.jpg 768w\" sizes=\"auto, (max-width: 840px) 100vw, 840px\" \/><\/p>\n<p style=\"text-align: justify\"><span class=\"dropcap\">T<\/span>ransition metal dichalcogenides (TMDs) are layered semiconductors with indirect band gaps comparable to Si. These compounds can be grown in large area, while their gap(s) can be tuned by changing their chemical composition or by applying a gate voltage. The experimental evidence collected so far points toward a strong interaction with light, which contrasts with the small photovoltaic efficiencies \u03b7 \u2264 1% extracted from bulk crystals or exfoliated monolayers. Here, we evaluate the potential of these compounds by studying the photovoltaic response of electrostatically generated <span class=\"caps\">PN<\/span>-junctions composed of approximately 10 atomic layers of MoSe2 stacked onto the dielectric h-<span class=\"caps\">BN<\/span>. In addition to ideal diode-like response, we find that these junctions can yield, under <span class=\"caps\">AM<\/span>-1.5 illumination, photovoltaic efficiencies \u03b7 exceeding 14%, with fill factors of \u223c70%. Given the available strategies for increasing \u03b7 such as gap tuning, improving the quality of the electrical contacts, or the fabrication of tandem cells, our study suggests a remarkable potential for photovoltaic applications based on TMDs. <a href=\"http:\/\/pubs.acs.org\/doi\/abs\/10.1021\/acs.nanolett.5b03265\" target=\"_blank\" rel=\"noopener\">[Full\u00a0article]<\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Transition metal dichalcogenides (TMDs) are layered semiconductors with indirect band gaps comparable to Si. These compounds can be grown in large area, while their gap(s) can be tuned by changing their chemical composition or by applying a gate voltage. The experimental evidence collected so far points toward a strong interaction with light, which contrasts with&hellip;<\/p>\n","protected":false},"author":15,"featured_media":138,"comment_status":"closed","ping_status":"closed","sticky":false,"template":"","format":"standard","meta":{"_mo_disable_npp":"","footnotes":""},"categories":[5],"tags":[21],"class_list":["post-137","post","type-post","status-publish","format-standard","has-post-thumbnail","hentry","category-articles","tag-semiconductors","entry"],"_links":{"self":[{"href":"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-json\/wp\/v2\/posts\/137","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-json\/wp\/v2\/posts"}],"about":[{"href":"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-json\/wp\/v2\/types\/post"}],"author":[{"embeddable":true,"href":"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-json\/wp\/v2\/users\/15"}],"replies":[{"embeddable":true,"href":"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-json\/wp\/v2\/comments?post=137"}],"version-history":[{"count":1,"href":"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-json\/wp\/v2\/posts\/137\/revisions"}],"predecessor-version":[{"id":139,"href":"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-json\/wp\/v2\/posts\/137\/revisions\/139"}],"wp:featuredmedia":[{"embeddable":true,"href":"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-json\/wp\/v2\/media\/138"}],"wp:attachment":[{"href":"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-json\/wp\/v2\/media?parent=137"}],"wp:term":[{"taxonomy":"category","embeddable":true,"href":"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-json\/wp\/v2\/categories?post=137"},{"taxonomy":"post_tag","embeddable":true,"href":"https:\/\/members.ifimac.uam.es\/fjgarcia\/wp-json\/wp\/v2\/tags?post=137"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}